What does the cryptic crossword clue "Number one in head after zero (6)" mean?

The definition is "Number". The wordplay uses a charade (building blocks). I (abbreviation of "Number one") + PATE (synonym of "head") + O (abbreviation of "zero") The answer is OPIATE.

Number one in head after zero (6)

Guardian Cryptic #29469 | 5 Down | 2024-08-23 flower

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